Synthesis and investigation of structure of complex of Cu(II) chloride with 2-amino-5- ethylthio-1,3,4-thiadiazole Исполнитель

Abstract. This paper presents the results on the synthesis and study of the structure of a new mononuclear complex of copper chloride with 2-amino 5-ethylthio-1,3,4-thiadiazole. Using the methods of IR spectroscopy and X-ray diffraction analysis, the structure of the complex was studied. It was shown that copper (II) chloride forms a five-coordination complex with a tetragonalpyramidal structure with 2-amino-5-ethylthio-1,3,4-thiadiazole, in the inner sphere of which four ligand molecules are coordinated to the complexing agent; the fifth position is occupied by a chlorine atom, the second chlorine atom is located in the outer sphere forming a cationic complex.